Ionic liquids for the nuclear industry: A radiochemical, structural, and electrochemical investigation

被引:0
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作者
Baston, GMN
Bradley, AE
Gorman, T
Hamblett, I
Hardacre, C
Hatter, JE
Healy, MJF
Hodgson, B
Lewin, R
Lovell, KV
Newton, GWA
Nieuwenhuyzen, M
Pitner, WR
Rooney, AW
Sanders, D
Seddon, KR
Simms, HE
Thied, RC
机构
[1] AEA Technol, Nucl Sci, Didcot OX11 0RA, Oxon, England
[2] Queens Univ Belfast, QUILL Res Ctr, Belfast BT9 5AG, Antrim, North Ireland
[3] Christie Hosp NHS Trust, Paterson Inst Canc Res, Manchester M20 4BX, Lancs, England
[4] British Nucl Fuels Plc, Res & Technol, Seascale CA20 1PG, Cumbria, England
[5] Cranfield Univ, JJ Thompson Irradiat Lab, Swindon SN6 8LA, Wilts, England
来源
IONIC LIQUIDS: INDUSTRIAL APPLICATIONS FOR GREEN CHEMISTRY | 2002年 / 818卷
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The applicability of ionic liquids within the nuclear industry has been investigated. The radiation stability of ionic liquids containing dialkylimidazolium cations has been tested through with alpha, beta and gamma irradiation. The results of these tests suggest that imidazolium salts have stabilities similar to alkylbenzenes and greater than tetrabutylphosphate / odorless kerosene (TBP/OK) mixtures. The oxidative dissolution of uranium dioxide and the anodic dissolution of uranium metal and plutonium metal have been carried out in various ionic liquid media (C) 2002 American Chemical Society.
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页码:162 / 177
页数:16
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