The role of isolated active centres in high-performance bioinspired selective oxidation catalysts

被引：7

作者：

Dzierzak, Joanna ^{[1
]}

Bottinelli, Emanuela ^{[1
]}

Berlier, Gloria ^{[1
]}

Gianotti, Enrica ^{[1
]}

Stulz, Eugen ^{[1
]}

Kowalczyk, Radoslaw Michal ^{[1
]}

Raja, Robert ^{[1
]}

机构：

[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 16期

基金：

英国工程与自然科学研究理事会;

关键词：

IRON; FRAMEWORK; COMPLEXES; METALS;

D O I：

10.1039/b926721b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transition-metal complexes containing amino acids encapsulated within solid supports generate isolated active centres that function as effective selective oxidation catalysts using benign oxidants such as air and display high turnovers and selectivity in industrially significant oxidation reactions.

引用

页码：2805 / 2807

页数：3

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