Photoelectrochemical Cell Based on Cup-Shaped Nanocarbon-Fullerene Composite Nanocluster Film: Enhancement of Photocurrent Generation by Cup-Shaped Nanocarbons as an Electron Transporter

被引:5
|
作者
Ohtani, Masataka [1 ]
Fukuzumi, Shunichi [1 ,2 ]
机构
[1] Osaka Univ, Dept Mat & Life Sci, Grad Sch Engn, SORST,Japan Sci & Technol Agcy, Suita, Osaka 5650871, Japan
[2] Ewha Womans Univ, Dept Bioinspired Sci, Seoul, South Korea
关键词
Clusterization; fullerene C60; nanocarbon; photoelectrochemical measurements; WALL CARBON NANOTUBES; SOLAR-ENERGY CONVERSION; PURIFICATION; NANOCOMPOSITES; ASSEMBLIES; PORPHYRIN; SIZE;
D O I
10.1080/15363831003782973
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cup-shaped nanocarbons and fullerene (C60) have been successfully organized as composite nanoclusters by using a rapid solvent mixing method. The resulting clusters were assembled on the nanostructured SnO2 electrode for photoelectrochemical measurements. This composite cluster film electrode afforded the drastic enhancement in the photoelectrochemical performance as well as the broader photoresponse in the visible region as compared with the reference system containing C60 cluster because of the efficient electron transport ability of cup-shaped nanocarbons. This makes cup-shaped nanocarbon materials a promising candidate for developing efficient photoelectrochemical and photovoltaic cells.
引用
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页码:251 / 260
页数:10
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