In-situ intercalation of VSe2(0001) with K:: direct observation of near-surface structure transformation by incoherent medium-energy electron diffraction
被引:12
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作者:
Pronin, II
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机构:
Russian Acad Sci, AF Ioffe Physicotech Inst, St Petersburg 194021, RussiaRussian Acad Sci, AF Ioffe Physicotech Inst, St Petersburg 194021, Russia
Pronin, II
[1
]
Gomoyunova, MV
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机构:Russian Acad Sci, AF Ioffe Physicotech Inst, St Petersburg 194021, Russia
Gomoyunova, MV
Faradzhev, NS
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机构:Russian Acad Sci, AF Ioffe Physicotech Inst, St Petersburg 194021, Russia
Faradzhev, NS
Valdaitsev, DA
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机构:Russian Acad Sci, AF Ioffe Physicotech Inst, St Petersburg 194021, Russia
Valdaitsev, DA
Starnberg, HI
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机构:Russian Acad Sci, AF Ioffe Physicotech Inst, St Petersburg 194021, Russia
Starnberg, HI
机构:
[1] Russian Acad Sci, AF Ioffe Physicotech Inst, St Petersburg 194021, Russia
[2] Univ Gothenburg, Dept Phys, SE-41296 Gothenburg, Sweden
[3] Chalmers Univ Technol, SE-41296 Gothenburg, Sweden
Auger electron spectroscopy;
surface structure;
morphology;
roughness and topography;
D O I:
10.1016/S0039-6028(00)00554-9
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
The intercalation of VSe2 with K is investigated in situ by a new technique for imaging the near-surface atomic structure, which is based on forward focusing of backscattered electrons. It is shown that room-temperature deposition of a few K monolayers on to the VSe2(0001) surface results in drastic changes of the crystal structure. Both a considerable expansion of the crystal lattice (the interlayer Se-Se distance is increased by 75%) and a transition from 1T to 3R(I) structure are revealed. (C) 2000 Elsevier Science B.V. All rights reserved.