MOF-derived iron as an active energy storage material for intermediate-temperature solid oxide iron-air redox batteries

被引：19

作者：

Zhang, Cuijuan ^{[1
,2
]}

Huang, Kevin ^{[1
]}

机构：

[1] Univ South Carolina, Dept Mech Engn, Columbia, SC 29208 USA

[2] Tianjin Univ, Sch Chem Engn & Technol, Tianjin 300350, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 76期

关键词：

PERFORMANCE; DURABILITY;

D O I：

10.1039/c7cc06131e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

here demonstrate that the iron derived from an iron-based metal-organic framework (MOF), with exposed high-density Fe-atom planes, exhibits improved reduction activity, enabling good rechargeability of solid oxide iron-air redox batteries at 500 degrees C. The discharge mass specific energies are 226.5 W h kg(-1)-Fe and 214.8Wh kg(-1)-Fe at C/4 and C/3, respectively, at a constant Fe-utilization of 20%.

引用

页码：10564 / 10567

页数：4

共 41 条

[1] Energy efficiency of an intermediate-temperature solid oxide iron-air redox battery
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[2] An Intermediate-Temperature Solid Oxide Iron-Air Redox Battery Operated on O2--Chemistry and Loaded with Pd-Catalyzed Iron-Based Energy Storage Material
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[9] Heat Balance in a Planar Solid Oxide Iron-Air Redox Battery: A Computational Analysis
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[10] All-Solid-State Iron-Air Batteries: A Promising High-Temperature Battery Technology for Large-Scale Energy Storage
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