Diffusion of macromolecules and water molecules in dilute aqueous solutions of polyethylene oxide

被引:0
|
作者
Sevryugin, VA [1 ]
Aslanyan, IY [1 ]
Skirda, VD [1 ]
机构
[1] Kazan State Univ, Kazan 420008, Tatarstan, Russia
来源
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2000年 / 74卷 / 12期
关键词
D O I
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中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The concentration dependences of the self-diffusion coefficients of water molecules D-aq(c) and polyethylene oxide macromolecules D-p(c) in aqueous solution are discussed. In the region of dilute solutions, the Daq(c) dependences are determined by the interaction of water molecules with polyethylene oxide oxygen atoms, and the D-p(C) dependences, by the interaction of polymer macromolecules with each other. These dependences are exponential functions of volume concentrations.
引用
收藏
页码:1973 / 1978
页数:6
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