Study on coke formation over Ni/γ-Al2O3, Co-Ni/γ-Al2O3, and Mg-Co-Ni/γ-Al2O3 catalysts for carbon dioxide reforming of methane

被引：108

作者：

Son, In Hyuk ^{[1
]}

Lee, Seung Jae ^{[2
]}

Song, In Yong ^{[3
]}

Jeon, Woo Sung ^{[3
]}

Jung, Insun ^{[3
]}

Yun, Dong Jin ^{[3
]}

Jeong, Dae-Woon ^{[4
]}

Shim, Jae-Oh ^{[4
]}

Jang, Won-Jun ^{[4
]}

Roh, Hyun-Seog ^{[4
]}

机构：

[1] Samsung Elect Co Ltd, Samsung Adv Inst Technol, Mat Res Ctr, Energy Mat Lab, Suwon 443803, Gyeonggi Do, South Korea

[2] Samsung Heavy Ind Co Ltd, Marine Res Inst, Gyeongsangnam Do 656710, South Korea

[3] Samsung Elect Co Ltd, Samsung Adv Inst Technol, Platform Technol Lab, Analyt Engn Grp, Suwon 443803, Gyeonggi Do, South Korea

[4] Yonsei Univ, Dept Environm Engn, Wonju 220710, Gangwon, South Korea

来源：

FUEL | 2014年 / 136卷

基金：

新加坡国家研究基金会;

关键词：

Carbon dioxide reforming of methane; Coke formation; Coke resistance; Decomposition/dissociation; GAS SHIFT REACTION; SIZED PT/CEO2 CATALYST; HYDROGEN-PRODUCTION; PARTIAL OXIDATION; SYNGAS PRODUCTION; NI CATALYSTS; CO2; MGO; STEAM; DEPOSITION;

D O I：

10.1016/j.fuel.2014.07.041

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Ni/gamma-Al2O3, CoNi/gamma-Al2O3, and MgCoNi/gamma-Al2O3 catalysts have been applied for the carbon dioxide reforming of methane reaction (CDR) and coke formation in the used catalysts has been investigated to understand the beneficial effect of Mg and Co. The MgCoNi/gamma-Al2O3 catalyst exhibits the highest catalytic performance (X-CH4 > 95% for 200 h) and has high coke resistance in CDR. This is due to the addition of Mg and Co accelerates the decomposition/dissociation of CH4 and CO2. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：194 / 200

页数：7

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