Examination of the Zener relationship between grain size and particle dispersion

Zener-Smith proposed the original relation R=4r/3f(v) in 1948, where R and r are the mean radii of the matrix grains and dispersed particles, and f(v) is the volume fraction of dispersed particles. They derived the relation under the assumption that the configuration of the grain boundary was independent of particle distribution. In the present work a modified relation R=4r/3f(v)(2/3) has been obtained by assuming that (1) the grain boundary is roughened by particle pinning, and (2) the amplitude of the roughness is lambda/2, where lambda is the inter-particle distance. Experimental data on the radii of austenite grains and the dispersed cementite particles in high C high Mn steels are shown to agree well with the modified relation.