Integrating Reaction Chemistry into Molecular Electronic Devices

被引：18

作者：

Shen, Qian ^{[1
]}

Guo, Xuefeng ^{[1
]}

Steigerwald, Michael L. ^{[2
,3
]}

Nuckolls, Colin ^{[2
,3
]}

机构：

[1] Peking Univ, BNLMS, State Key Lab Struct Chem Unstable & Stable Speci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

[2] Columbia Univ, Dept Chem, New York, NY 10027 USA

[3] Columbia Univ, Ctr Elect Mol Nanostruct, New York, NY 10027 USA

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2010年 / 5卷 / 05期

基金：

美国国家科学基金会;

关键词：

bottom-up assembly; molecular devices; nanoscience; semiconductors; top-down fabrication; SELF-ASSEMBLED MONOLAYERS; CARBON NANOTUBES; JUNCTION CONDUCTANCE; TRANSPORT JUNCTIONS; CONJUGATED MOLECULES; ELECTRICAL DETECTION; WIRE; THIOLS; LITHOGRAPHY; FLUCTUATION;

D O I：

10.1002/asia.200900565

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This Focus Review provides an overview of the design and fabrication of new families of molecular electronic devices where reaction chemistry is an efficient means for covalently bridging the nanogaps between separated contacts. In each case ever-reducing top-down device fabrication existing in the silicon-based semiconductor industry is tailored to meet the requirements of ever-expanding length scales of bottom-up assembly. The combination of directed self-assembly and programmed chemical reactions with device fabrication allows us to modify the electrodes and then to complete electrical circuits by chemically connecting the electrodes.

引用

页码：1040 / 1057

页数：18

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