A Water-Stable 3D Luminescent Metal-Organic Framework Based on Heterometallic [Eu6IIIZnII] Clusters Showing Highly Sensitive, Selective, and Reversible Detection of Ronidazole

被引：136
|
作者：
Zhang, Qingfu [1 ]
Lei, Mingyuan [1 ]
Yan, Hui [1 ]
Wang, Jinyun [2 ]
Shi, Yang [1 ]
机构：
[1] Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
来源：
INORGANIC CHEMISTRY | 2017年 / 56卷 / 14期
关键词：
NITROAROMATIC EXPLOSIVES; COORDINATION POLYMERS; AQUEOUS-MEDIUM; PICRIC ACID; PHOTOLUMINESCENCE; CATIONS; SENSOR; SERIES; FILMS; IONS;
D O I：
10.1021/acs.inorgchem.7b01156
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A water-stable 3D luminescent metal organic framework (MOP), [Eu6Zn(mu 3-OH)(8)(NDC)(6)(H2O)(6)] (1), constructed from heterometallic [(Eu6ZnII)-Zn-III] clusters and electron-rich pi-conjugated 1,4-naphthalenedicarboxylic acid (H2NDC) ligands exhibits highly sensitive, selective, and reversible detection of ronidazole, which represents the first example of luminescent MOFs based on Ln-TM heterometallic clusters for the detection of antibiotics in aqueous solution.
引用
收藏
页码：7610 / 7614
页数：5
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