(μ-biphenyl-4,4′-dicarboxylato)bis[(2-amino-pyridine)silver(I)]

被引：4
|
作者：
Liu, ZD [1 ]
Zhu, HL
机构：
[1] Fuyang Normal Coll, Dept Chem, Fuyang Anhui 236041, Peoples R China
[2] Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2004年 / 60卷
关键词：
D O I：
10.1107/S1600536804028624
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [ Ag-2( C14H8O4)( C5H6N2) (2)], is a dinuclear Ag-I complex which has crystallographic inversion symmetry. Each Ag atom is three- coordinated by two N atoms from two 2- aminopyridine ligands and by one O atom from a biphenyl-4,4'- dicarboxylate ligand, giving a Y- shaped coordination environment. Two Ag I atoms are linked through a biphenyl-4,4'- dicarboxylate ligand, acting as a bridge, forming a dimeric complex. The separation between the two silver( I) centres is 15.879 ( 3) Angstrom. In the crystal structure, molecules are connected by N - H ... O hydrogen bonds, forming molecular tapes in the a- axis direction.
引用
收藏
页码：M1866 / M1868
页数：3
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