Lithiation and magnesiation of R5Sn3 (R = Y and Gd) alloys

被引：6
|
作者：
Kowalczyk, G. [1 ]
Kordan, V. [2 ]
Stetskiv, A. [3 ]
Pavlyuk, V. [1 ,2 ]
机构：
[1] Czestochowa Jan Dlugosz Univ, Inst Chem Environm Protect & Biotechnol, Al Armii Krajowej 13-15, PL-42200 Czestochowa, Poland
[2] Ivan Franko Lviv Natl Univ, Dept Inorgan Chem, Kyryla i Mefodia 6, UA-79005 Lvov, Ukraine
[3] Ivano Frankivsk Natl Med Univ, Dept Chem, Galyska Str 2, UA-76018 Ivano Frankivsk, Ukraine
来源：
INTERMETALLICS | 2016年 / 70卷
关键词：
Intermetallic compounds; Crystal structure; Solid state electrochemistry; CRYSTAL-STRUCTURE; ELECTROCHEMICAL LITHIATION; TERNARY-SYSTEM; LITHIUM; BATTERIES; ANODE; PHASE; TIN;
D O I：
10.1016/j.intermet.2015.12.004
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The lithiation and magnesiation of binary R5Sn3 (R = Y and Gd) phases has been studied by XRD, SEM, EPMA and electrochemical methods. The formation of R(5)Sn(3)Lix and R(5)Sn(3)Mgx ternary hexagonal phases as the results of insertion of Li/Mg into octahedral voids were observed during the first stage of electrochemical lithiation and magnesiation respectively. During the second stage of the electrochemical lithiation and magnesiation is the decomposition of the hexagonal phase into new phases and substitution of tin atoms by Li/Mg are observed. (C) 2015 Published by Elsevier Ltd.
引用
收藏
页码：53 / 60
页数：8
相关论文
共 50 条
  • [1] Magnetic properties of R3Co8Sn4 (R = Y, Gd)
    Canepa, F
    Napoletano, M
    Manfrinetti, P
    Palenzona, A
    Cirafici, S
    Merlo, F
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2000, 220 (01) : 39 - 44
  • [2] Magnetic properties of R3Cu4Sn4 (R=Ce, Gd and Y)
    Singh, S
    Dhar, SK
    Manfrinetti, P
    Palenzona, A
    JOURNAL OF ALLOYS AND COMPOUNDS, 2000, 298 (1-2) : 68 - 72
  • [3] Substitution effects on magnetic properties of Gd-R (R=Y, Zr) alloys
    Kaji, S.
    Kobayashi, T.
    Saito, A. T.
    INTERNATIONAL CONFERENCE ON MAGNETISM (ICM 2009), 2010, 200
  • [4] Magnetic transition and magnetocaloric effect of R5(Si, Sn)3 (R = Pr, Nd) alloys
    Yao, Guiquan
    Chong, He
    Chen, Yansong
    Wang, Qiang
    Zhu, Jie
    Yang, Sen
    Cui, Weibin
    SOLID STATE COMMUNICATIONS, 2022, 342
  • [5] R-M interactions in R(2)BaMO(5) (R=Y or Gd; M=Cu or Zn)
    Goya, GF
    Mercader, RC
    Steren, LB
    Sanchez, RD
    Causa, MT
    Tovar, M
    JOURNAL OF PHYSICS-CONDENSED MATTER, 1996, 8 (25) : 4529 - 4537
  • [6] X-ray investigation of the R-Fe-Sn ternary systems (R-Y, Gd)
    Mudryk, Y
    Romaka, L
    Stadnyk, Y
    Bodak, O
    Fruchart, D
    JOURNAL OF ALLOYS AND COMPOUNDS, 2004, 383 (1-2) : 162 - 165
  • [7] New structures formed by R3Au4Sn3, R5Au8Sn5 and R3Au6Sn5 compounds (R = rare earths)
    Fornasini, M. L.
    Mazzone, D.
    Provino, A.
    Michetti, M.
    Paudyal, D.
    Gschneidner, K. A., Jr.
    Manfrinetti, P.
    INTERMETALLICS, 2014, 53 : 169 - 176
  • [8] Magnetic properties of R2 BaCuO5 (R = Y, Gd, Yb)
    Tagaya, K
    Yokoo, T
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2000, 210 (1-3) : 203 - 207
  • [9] Crystallographic, magnetic and electrical characteristics of R3Ni8Sn4 compounds (R = Y, Nd, Sm, Gd, and Tb)
    Romaka, V. V.
    Romaka, L.
    Romaniv, I.
    Hlil, E. K.
    Rykavets, Z.
    Kuzhel, B.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 701 : 358 - 365
  • [10] Ternary compounds in iron-rich R-Fe-Si alloys (R = Y, Nd, Gd)
    Ivanova, G.V.
    Makarova, G.M.
    Shcherbakova, E.V.
    Belozerov, E.V.
    Fizika Metallov i Metallovedenie, 2002, 93 (04): : 71 - 74
12345