Synthesis and competency of a tartrate-derived dicationic solid-liquid phase-transfer catalyst

被引：18
|
作者：
Rueffer, ME [1 ]
Fort, LK [1 ]
MacFarland, DK [1 ]
机构：
[1] Gettysburg Coll, Dept Chem, Gettysburg, PA 17325 USA
来源：
TETRAHEDRON-ASYMMETRY | 2004年 / 15卷 / 20期
关键词：
D O I：
10.1016/j.tetasy.2004.09.004
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new asymmetric phase-transfer catalyst is described, along with a new, flexible synthetic scheme using a tartaric acid chloride. Alkylations and Michael reactions on a glycine imino ester show the new catalyst to be an effective phase-transfer catalyst with limited enantioselectivity. (C) 2004 Published by Elsevier Ltd.
引用
收藏
页码：3297 / 3300
页数：4
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