N-Arylation of indole and aniline by a green synthesized CuO nanoparticles mediated by Thymbra spicata leaves extract as a recyclable and heterogeneous nanocatalyst

被引：30
|
作者：
Veisi, Hojat [1 ]
Hemmati, Saba [1 ]
Javaheri, Hadis [1 ]
机构：
[1] Payame Noor Univ, Dept Chem, Tehran, Iran
来源：
TETRAHEDRON LETTERS | 2017年 / 58卷 / 32期
关键词：
Green Chemistry; Ullmann; Heterogeneous nanocatalyst; Thymbra spicata; Copper oxide; MAGNETIC FE3O4 NANOPARTICLES; MIYAURA COUPLING REACTIONS; PALLADIUM NANOPARTICLES; CATALYTIC-ACTIVITY; CORE/SHELL NANOSTRUCTURE; IMMOBILIZED PALLADIUM; EFFICIENT LIGAND; ARYL; AMINES; ANTIBACTERIAL;
D O I：
10.1016/j.tetlet.2017.06.086
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In a biological procedure where the aqueous leaves extract of Thymbra spicata was utilized as a reducing and capping agent, copper oxide (CuO) nanoparticles (NPs) were synthesized. These CuO NPs were characterized via Fourier transformed infrared spectroscopy (FT-IR), X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), energy dispersive Xray spectroscopy (EDS), wavelength-dispersive X-ray spectroscopy (WDX), and UV-visible spectroscopy. The as prepared nanoparticles have been employed as an appropriate nanocatalyst for ligand-free N-arylation of indole and aniline via Ullmann-type C-N coupling reactions. Adequate to outstanding quantities of the N-arylated products were synthesized and the nanocatalyst was retrievable and reusable seven times without noticeable decrease in catalytic performance. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3155 / 3159
页数：5
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  • [1] Green synthesis of the silver nanoparticles mediated by Thymbra spicata extract and its application as a heterogeneous and recyclable nanocatalyst for catalytic reduction of a variety of dyes in water
    Veisi, Hojat
    Azizi, Sirous
    Mohammadi, Pourya
    [J]. JOURNAL OF CLEANER PRODUCTION, 2018, 170 : 1536 - 1543
  • [2] Green Synthesis of Pd Nanoparticles Mediated by Thymbra Spicata Leaves Extract and Its Application as a Recyclable Nanocatalyst for Reduction of 4-Nitrophenol and Suzuki Reactions
    Tanreh, Sepideh
    Hallajian, Sara
    Hamedani, Yasaman Pourdakheli
    Nazari, Pooneh
    Darvishi, Kiana
    Hekmati, Malak
    [J]. JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2018, 28 (03) : 1001 - 1010
  • [3] Green Synthesis of Pd Nanoparticles Mediated by Thymbra Spicata Leaves Extract and Its Application as a Recyclable Nanocatalyst for Reduction of 4-Nitrophenol and Suzuki Reactions
    Sepideh Tanreh
    Sara Hallajian
    Yasaman Pourdakheli Hamedani
    Pooneh Nazari
    Kiana Darvishi
    Malak Hekmati
    [J]. Journal of Inorganic and Organometallic Polymers and Materials, 2018, 28 : 1001 - 1010
  • [4] Green synthesis of predominant (111) facet CuO nanoparticles: Heterogeneous and recyclable catalyst for N-arylation of indoles
    Suramwar, Nikhil V.
    Thakare, Sanjay R.
    Karade, Nandkishor N.
    Khaty, Niren T.
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2012, 359 : 28 - 34
  • [5] Chitosan nanoparticles functionalized poly-2-hydroxyaniline supported CuO nanoparticles: An efficient heterogeneous and recyclable nanocatalyst for N-arylation of amines with phenylboronic acid at ambient temperature
    Seyedi, Neda
    Zahedifar, Mahboobeh
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2021, 35 (10)
  • [6] Electrospun copper oxide nanoparticles as an efficient heterogeneous catalyst for N-arylation of indole
    Khalil, Abdullah
    Fihri, Aziz
    Jouiad, Mustapha
    Hashaikeh, Raed
    [J]. TETRAHEDRON LETTERS, 2014, 55 (43) : 5973 - 5975
  • [7] Green synthesis of CuO nanoparticles using aqueous extract of Thymus vulgaris L. leaves and their catalytic performance for N-arylation of indoles and amines
    Nasrollahzadeh, Mahmoud
    Sajadi, S. Mohammad
    Rostami-Vartooni, Akbar
    Hussin, Sarbast Mamand
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2016, 466 : 113 - 119
  • [8] Ceria-supported copper nanoparticles: A highly efficient and recyclable catalyst for N-arylation of indole
    Amadine, Othmane
    Maati, Houda
    Abdelouhadi, Karima
    Fihri, Aziz
    El Kazzouli, Said
    Len, Christophe
    El Bouari, Abdeslam
    Solhy, Abderrahim
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2014, 395 : 409 - 419
  • [9] CuO Nanoparticles: A Simple, Effective, Ligand Free, and Reusable Heterogeneous Catalyst for N-Arylation of Benzimidazole
    Babu, Sundaram Ganesh
    Karvembu, Ramasamy
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (16) : 9594 - 9600
  • [10] Biosynthesis of CuO nanoparticles using Rosa canina fruit extract as a recyclable and heterogeneous nanocatalyst for C-N Ullmann coupling reactions
    Hemmati, Saba
    Mehrazin, Lida
    Hekmati, Malak
    Izadi, Maryam
    Veisi, Hojat
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2018, 214 : 527 - 532
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