Iodine-Catalyzed Chemoselective Hydroamination Reaction Using 5-Mercaptotetrazoles Derivatives

被引：10

作者：

Siddaraju, Yogesh ^{[1
]}

Prabhu, Kandikere Ramaiah ^{[1
]}

机构：

[1] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India

来源：

ACS OMEGA | 2018年 / 3卷 / 05期

关键词：

DEHYDROGENATIVE COUPLING REACTION; DIMETHYL-SULFOXIDE; C-H; ALKENES; HYDROTHIOLATION; HYDROARYLATION; SULFENYLATION; STYRENES; OXIDANT; KETONES;

D O I：

10.1021/acsomega.8b00499

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-free chemoselective hydroamination of styrene derivatives has been achieved with high chemo-selectivity over sulfenylation of 1H-tetrazole-5-thiol using a catalytic amount of iodine. The scope of this methodology has been extended for the hydroamination of a-substituted styrene derivatives. This reaction involves a single-step C-N-bond formation under atom economical process. This eco-friendly method uses readily available and inexpensive iodine in a catalytic amount.

引用

页码：4908 / 4917

页数：10

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