Despite the presence of a huge amount of potassium (K+) in the soil, most of the soils are deficient in plant available K+. A large amount of the K+ is fixed by clay minerals present in such soils and cannot be taken up by plants to achieve optimum plant growth. In such type of soils, large amount of K+ fertilizers are required for optimum plant growth, as plants do not respond enough to a normally recommended K+ fertilization. Vermiculite clay minerals can fix an enormous amount of applied K+, which becomes slowly available to the plants. The K+ dynamics in such soils are valuable to recommend K+ fertilizer requirements for sustainable nutrient management. We analyzed the K+ dynamics of three alluvial soils, i.e Kleinlinden, Giessen and Trebur, collected from Germany and found that the soils with vermiculite and smectite clay minerals have more K+-fixing ability than soils dominated by illite clay minerals. However, as the K+ concentration decreased in the soil solution, smectite-dominant soils may easily release fixed K+ due to lower particle-charge, whereas vermiculite and illite dominant soils may not release fixed K+ easily. Moreover, ammonium exchangeable K+, non-exchangeable K+, total K+ and K+-fixing capacity of these soils are directly proportional to the soil clay contents. While recommending K+ fertilizers clay contents and the type of clay minerals is not considered and recommended K+ fertilizers sometimes do not response plant growth enhancement. Therefore potassium fertilizer should be recommended by taking into consideration the type and amount of clay minerals present in the soil.