Luminescence intensity enhancement of Eu2+ and Eu3+ by Tb3+ in LiLa9(SiO4)6O2

被引:8
|
作者
Xie, Mubiao [1 ]
Zhu, Guoxian [1 ]
Pan, Rongkai [1 ]
Li, Dongyu [2 ]
Hou, Dejian [3 ]
机构
[1] Lingnan Normal Univ, Inst Phys Chem, Sch Chem & Chem Engn, Zhanjiang 524048, Peoples R China
[2] Lingnan Normal Univ, Sch Phys Sci & Technol, Zhanjiang 524048, Peoples R China
[3] Jiangxi Univ Sci & Technol, Sch Met & Chem Engn, Ganzhou 341000, Jiangxi, Peoples R China
基金
中国国家自然科学基金;
关键词
luminescence; LiLa9(SiO4)(6)O-2; LEDs; Eu; Tb3+; ENERGY-TRANSFER; PHOTOLUMINESCENCE PROPERTIES; PHOSPHOR; SENSITIZATION; EMISSION;
D O I
10.1088/0022-3727/49/22/225105
中图分类号
O59 [应用物理学];
学科分类号
摘要
Novel yellow-emitting phosphors LiLa9(SiO4)(6)O-2: 0.05Eu, xTb (x = 0, 0.01, 0.03, 0.02, 0.04, 0.06, 0.08, 0.10) were prepared by a solid-state reaction in a CO-reducing atmosphere. The excitation and emission spectra, and the fluorescence decays were measured and discussed in detail. The fluorescence spectra results of sample LiLa9(SiO4)(6)O-2: 0.05Eu reveal that still a small amount of Eu3+ ions are detected in the LiLa9(SiO4)(6)O-2 host. The introduction of Tb3+ ions can enhance the emission intensity of LiLa9(SiO4)(6)O-2: 0.05Eu under near-ultraviolet light excitation but they do not vary the emission color much. The results indicate that the yellow-emitting phosphors LiLa9(SiO4)(6)O-2: Eu, Tb can be considered as potential phosphor-converted materials for n-UV white light-emitting diodes.
引用
收藏
页数:8
相关论文
共 50 条
  • [1] Optical spectroscopy of Nd3+ in LiLa9(SiO4)6O2 crystals
    Cavalli, Enrico
    Calestani, Gianluca
    Belletti, Alessandro
    Bettinelli, Marco
    Speghini, Adolfo
    [J]. OPTICAL MATERIALS, 2009, 31 (09) : 1340 - 1342
  • [2] Luminescence of LiLa9(SiO4)6O2 Silicate Crystals Doped with Ce3+ and Pr3+ Ions
    Miroshnichenko, D. V.
    Pustovarov, V. A.
    [J]. IV INTERNATIONAL YOUNG RESEARCHERS' CONFERENCE: PHYSICS, TECHNOLOGIES AND INNOVATION (PTI-2017), 2017, 1886
  • [3] White emitting Ca2Tb8(SiO4)6O2:Eu2+/Eu3+ phosphors: Photoluminescence and efficient energy transfer
    Yang, Che-Yuan
    Das, Subrata
    Som, Sudipta
    Lu, Chung-Hsin
    [J]. CHEMICAL PHYSICS LETTERS, 2016, 660 : 164 - 168
  • [4] Luminescence properties of a novel promising red phosphor LiY9(SiO4)6O2:EU3+
    Zhang, Zhi-wei
    Wang, Li-jiang
    Yang, Sha-sha
    Chen, Wei-guang
    Chu, Xiu-juan
    Wang, Dong-jun
    [J]. MATERIALS LETTERS, 2017, 204 : 101 - 103
  • [5] Luminescence enhancement of Tb3+ in Sr3SiO5:Eu2+ phosphor
    Lei, Xiaomin
    Li, Zhu
    Du, Yanrong
    He, Diping
    Wang, Yanjing
    Li, Liya
    Jiao, Huan
    [J]. JOURNAL OF MATERIALS SCIENCE, 2013, 48 (14) : 4860 - 4865
  • [6] Luminescence enhancement of Tb3+ in Sr3SiO5:Eu2+ phosphor
    Xiaomin Lei
    Zhu Li
    Yanrong Du
    Diping He
    Yanjing Wang
    Liya Li
    Huan Jiao
    [J]. Journal of Materials Science, 2013, 48 : 4860 - 4865
  • [7] Crystal structure and optical spectra of LiLa9(SiO4)6O2 crystals activated with Er3+
    Bettinelli, Marco
    Speghini, Adolfo
    Falcomer, Daniele
    Cavalli, Enrico
    Calestani, Gianluca
    Quintanilla, Marta
    Cantelar, Eugenio
    Cusso, Fernando
    [J]. JOURNAL OF LUMINESCENCE, 2008, 128 (5-6) : 738 - 740
  • [8] Ce3+,Tb3+,Eu3+,Mn2+-doped and Codoped NaY9(SiO4)6O2 Phosphors: Luminescence, Energy Transfer, Tunable Color Properties
    Lv, Wenzhen
    Jia, Yongchao
    Lu, Wei
    Zhao, Qi
    Jiao, Mengmeng
    Shao, Baiqi
    You, Hongpeng
    [J]. ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY, 2014, 3 (02) : R9 - R13
  • [9] Synthesis and spectroscopic investigations of Sr2Y8(SiO4)6O2:Eu2+, Eu3+ phosphor for white LEDs
    Sokolnicki, Jerzy
    Zych, Eugeniusz
    [J]. JOURNAL OF LUMINESCENCE, 2015, 158 : 65 - 69
  • [10] Eu2+/Eu3+ co-activated Ba2La8(SiO4)6O2 phosphors for optical thermometry
    Cheng, Ju
    Zhang, Sheng
    Cheng, Jinlong
    Ma, Pengcheng
    Yu, Hualing
    Zhai, Zhangyin
    [J]. JOURNAL OF LUMINESCENCE, 2024, 275