Forensic potential of comprehensive two-dimensional gas chromatography

被引:42
|
作者
Sampat, Andjoe [1 ]
Lopatka, Martin [2 ,3 ]
Sjerps, Marjan [2 ,3 ,4 ]
Vivo-Truyols, Gabriel [1 ]
Schoenmakers, Peter [1 ,4 ]
van Asten, Arian [1 ,3 ,4 ]
机构
[1] Univ Amsterdam, Fac Sci, Vant Hoff Inst Mol Sci, POB 94157, NL-1090 GD Amsterdam, Netherlands
[2] Univ Amsterdam, Fac Sci, Korteweg de Vries Inst Math, POB 94248, NL-1090 GE Amsterdam, Netherlands
[3] Netherlands Forens Inst, POB 24044, NL-2490 AA The Hague, Netherlands
[4] Amsterdam Ctr Forens Sci & Med, CLHC, POB 94157, NL-1090 GD Amsterdam, Netherlands
关键词
Forensic science; Comprehensive two-dimensional gas; chromatography; Mass spectrometry; GC X GC; GC X GC-MS; Data analysis; Review; FLIGHT MASS-SPECTROMETRY; VOLATILE ORGANIC-COMPOUNDS; X GC-TOFMS; RETENTION TIME ALIGNMENT; LIKELIHOOD RATIO MODEL; BASE-LINE CORRECTION; PEAK-DETECTION; MIXTURE-MODELS; NERVE-AGENT; FIRE DEBRIS;
D O I
10.1016/j.trac.2015.10.011
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this study, the application of comprehensive two-dimensional (2D) gas chromatography (GC X GC) in forensic science is reviewed. The peer-reviewed publications on the forensic use of GC X GC and 2D gas chromatography with mass spectrometric detection (GC X GC-MS) have been studied in detail, not only to provide an overview, but also to analyze and understand the potential and limitations of this relatively novel analytical technique in forensic investigations. In order to make comprehensive GC X GC a powerful tool in forensic laboratories involved in chemical analysis, further developments are needed with respect to data analysis. Easy-to-use and "fit-for-forensic purpose" data analysis and chemometric tools will allow forensic analytical chemists to explore and compare the comprehensive data to provide solutions for relevant questions in criminal investigations. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:345 / 363
页数:19
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