Poly(schiff's bases)-bifluorophores: Synthesis, photophysical properties, non-radiational transfer of energy of electronic excitation

被引:0
|
作者
Siling, SA
Shamshin, SV
Ronova, IA
Kovalevski, AY
Grachev, AB
Tsiganova, OY
Yuzhakov, VI
机构
[1] Russian Acad Sci, Inst Organoelement Cpds, Moscow 119991, Russia
[2] Moscow MV Lomonosov State Univ, Fac Phys, Moscow 119899, Russia
来源
OXIDATION COMMUNICATIONS | 2004年 / 27卷 / 04期
关键词
flurophores; poly(schiff) bases; polycondensation; synthesis; fluorescence;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
For the first time poly(schiffs bases)-fluorophores with self-fluorescense were synthesised by polycondensation of dialdehydes of dicarboxylic acids and diamines-fluorophores. It was shown that the solutions of these polymers have abnormally high for polymer solutions quantum yield of fluorescence reaching 80% at 20degreesC. High quantum yield of fluorescence is the result of high rigidity of polymer chain. Poly(schiff's bases)-bifluorophores were synthesised and it was shown that in these polymers non-radiative transfer of energy of electron excitation takes place with coefficient or energy transfer reaching 84%.
引用
收藏
页码:777 / 787
页数:11
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