Photocatalytic activity of anatase-brookite TiO2 nanoparticles synthesized by sol gel method at low temperature

被引:41
|
作者
Nachit, W. [1 ,2 ]
Ahsaine, H. Ait [3 ]
Ramzi, Z. [4 ]
Touhtouh, S. [2 ]
Goncharova, I. [5 ]
Benkhouja, K. [1 ,6 ]
机构
[1] Chouaib Doukkali Univ, Fac Sci, Dept Chem, LCCA E2M, BO BOX 20, El Jadida 24000, Morocco
[2] Chouaib Doukkali Univ, Natl Sch Appl Sci ENSAJ, LabSIPE, POB 1166,Plateau, El Jadida 24002, Morocco
[3] Mohammed V Univ Rabat, Fac Sci, Ctr Mat Sci, LCAM, Rabat, Morocco
[4] Cadi Ayyad Univ, Fac Sci, Dept Chem, SCiMATOP, POB 2390, Safi, Morocco
[5] Kyiv Natl Univ Trade & Econ, Dept Commod Sci Safety & Qual Management, Kiev, Ukraine
[6] Cadi Ayyad Univ, LMPEQ Natl Sch Appl Sci ENSAS, POB 63, Safi 46000, Morocco
关键词
Anatase-brookite TiO 2; Sol-gel; Nanocristallites; Photocatalysis; Rhodamine B; PHASE; DEGRADATION; RUTILE;
D O I
10.1016/j.optmat.2022.112256
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
TiO2 photocatalysis is widely used in a variety of applications and products in the environmental and energy fields, including self-cleaning surfaces, air and water purification systems, sterilization, hydrogen evolution, and photoelectrochemical conversion. In this paper TiO2 nanoparticle was investigated for the degradation of Rhodamine B (RhB) under UV light. Nanocrystalline Anatase-Brookite TiO2 catalyst was synthesized via sol-gel method using the Titanium tetraisopropoxide (TTIP) at a temperature of 50 degrees C under mild conditions. XRD, TEM, SEM, FT-IR and BET were applied to characterize the crystal phase. The Crystalline size of TiO2 powder has been obtained with diameter <30 nm at 500 degrees C using an acid. The photocatalytic activity of TiO2 nanoparticle show that the degradation of Rhodamine B under UV light have removal of 95% dye was degraded in 60min.
引用
收藏
页数:5
相关论文
共 50 条
  • [1] Sol-gel synthesis of mesoporous anatase-brookite and anatase-brookite-rutile TiO2 nanoparticles and their photocatalytic properties
    Mutuma, Bridget K.
    Shao, Godlisten N.
    Kim, Won Duck
    Kim, Hee Taik
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2015, 442 : 1 - 7
  • [2] Nd/TiO2 Anatase-Brookite Photocatalysts for Photocatalytic Decomposition of Methanol
    Koci, Kamila
    Troppova, Ivana
    Reli, Martin
    Matejova, Lenka
    Edelmannova, Miroslava
    Drobna, Helena
    Dubnova, Lada
    Rokicinska, Anna
    Kustrowski, Piotr
    Capek, Libor
    [J]. FRONTIERS IN CHEMISTRY, 2018, 6
  • [3] Biphasic anatase-brookite nanoparticles prepared by sol-gel complex synthesis and their photocatalytic activity in hydrogen production
    Cihlar, Jaroslav
    Kasparek, Vit
    Kralova, Marcela
    Castkova, Klara
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (07) : 2950 - 2962
  • [4] Facile method to obtain anatase and anatase-brookite nanoparticles (TiO2) with MWCNT towards reducing the bandgap
    Rosado, Gabriel
    Maria Valenzuela-Muniz, Ana
    Miki-Yoshida, Mario
    Verde Gomez, Ysmael
    [J]. DIAMOND AND RELATED MATERIALS, 2020, 109
  • [5] Comparison of optical and electrochemical properties of anatase and brookite TiO2 synthesized by the sol-gel method
    Koelsch, M
    Cassaignon, S
    Guillemoles, JF
    Jolivet, JR
    [J]. THIN SOLID FILMS, 2002, 403 : 312 - 319
  • [6] Investigation of photocatalytic activity of TiO2 nanoparticles synthesized by sol–gel technique
    G. K. Sukhadeve
    S. Y. Janbandhu
    S. Upadhyay
    R. S. Gedam
    [J]. Journal of the Australian Ceramic Society, 2022, 58 : 39 - 48
  • [7] Simple Fabrication of Anatase-Brookite Mixed-Phase TiO2 Nanoparticles with Visible-Light Responsive Photocatalytic Activity
    Xue, Bin
    Sun, Tao
    Wu, Ji-Kui
    [J]. ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (05) : 2073 - 2076
  • [8] Enhanced visible light photocatalytic activity of Cr3+-doped anatase TiO2 nanoparticles synthesized by sol–gel method
    H. M. Yadav
    T. V. Kolekar
    A. S. Barge
    N. D. Thorat
    S. D. Delekar
    B. M. Kim
    B. J. Kim
    J. S. Kim
    [J]. Journal of Materials Science: Materials in Electronics, 2016, 27 : 526 - 534
  • [9] Sol–gel solvothermal route to synthesize anatase/brookite/rutile TiO2 nanocomposites with highly photocatalytic activity
    Xin Qian
    Huanre Han
    Yulong Chen
    Ye Yuan
    [J]. Journal of Sol-Gel Science and Technology, 2018, 85 : 394 - 401
  • [10] Low-temperature synthesis of anatase-brookite composite nanocrystals: the junction effect on photocatalytic activity
    Ozawa, T
    Iwasaki, M
    Tada, H
    Akita, T
    Tanaka, K
    Ito, S
    [J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 281 (02) : 510 - 513