Synthesis of chiral, densely functionalized medium-sized rings from carbohydrate precursors via regioselective exo/endo-primary alkyl radical cyclizations

被引：27

作者：

Marco-Contelles, J ^{[1
]}

de Opazo, E ^{[1
]}

机构：

[1] CSIC, Lab Radicales Libres, E-28006 Madrid, Spain

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 28期

关键词：

D O I：

10.1016/S0040-4039(00)00837-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first 8-endo-trig and 7-exo-dig carbocyclizations of primary alkyl free radicals on acyclic carbohydrate templates derived from D-glucose, leading to chiral and polyfunctionalized medium-sized carbocycles are described. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：5341 / 5345

页数：5