Highly efficient green synthesis of α-hydroxyphosphonates using a recyclable choline hydroxide catalyst

被引：20

作者：

Kalla, Reddi Mohan Naidu ^{[1
]}

Zhang, Yu ^{[1
]}

Kim, Il ^{[1
]}

机构：

[1] Pusan Natl Univ, Dept Polymer Sci & Engn, PLUS Ctr Adv Chem Technol BK21, Busan 609735, South Korea

来源：

NEW JOURNAL OF CHEMISTRY | 2017年 / 41卷 / 13期

基金：

新加坡国家研究基金会;

关键词：

PHOSPHO SULFONIC-ACID; SOLVENT-FREE; PHOSPHORORGANISCHE VERBINDUNGEN; IONIC LIQUIDS; ALDEHYDES; INHIBITORS; HYDROPHOSPHONYLATION; DERIVATIVES; PROTOCOL; KETONES;

D O I：

10.1039/c6nj03948k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Choline hydroxide has been found to be an efficient basic ionic liquid catalyst for the synthesis of alpha-hydroxyphosphonates. Hydrophosphonylation of aldehydes was performed via the nucleophilic addition of diethylphosphite to aldehydic carbonyl compounds, in the presence of choline hydroxide under neat as well as solvent conditions. A wide array of substrates, including aromatic, fused aromatic, and heterocyclic aldehydes, were efficiently converted to their corresponding products in good yields. This protocol provides an alternative method for the straightforward synthesis of alpha-hydroxyphosphonates in high yields.

引用

页码：5373 / 5379

页数：7

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