Computational Study of C-H Insertion Reactions with Ethyl Bromodiazoacetate

被引：17
|
作者：
Bonge, Hanne Therese [1 ]
Hansen, Tore [1 ]
机构：
[1] Univ Oslo, Dept Chem, N-0315 Oslo, Norway
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 2010卷 / 23期
关键词：
Computational chemistry; Insertion; Reaction mechanisms; Carbenoids; Rhodium; RHODIUM CARBENOIDS; DIAZO COMPOUND; ACTIVATION; FUNCTIONALIZATION; MECHANISM;
D O I：
10.1002/ejoc.201000531
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A computational study of C-H insertion reactions between ethyl bromodiazoacetate and three different substrates is presented The mechanism of the C-H insertion is shown to be substrate dependent, the reaction follows either a concerted mechanism or a two-step mechanism in which complete hydride transfer precedes C-C bond formation
引用
收藏
页码：4355 / 4359
页数：5
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