Asymmetric Organocatalysis in Deep Eutectic Solvents

被引：40

作者：

Alonso, Diego A. ^{[1
,2
]}

Burlingham, Sarah-Jayne ^{[1
,2
]}

Chinchilla, Rafael ^{[1
,2
]}

Guillena, Gabriela ^{[1
,2
]}

Ramon, Diego J. ^{[1
,2
]}

Tiecco, Matteo ^{[3
]}

机构：

[1] Alicante Univ, Dept Organ Chem, POB 99, Alicante 03080, Spain

[2] Alicante Univ, Inst Organ Synth, POB 99, Alicante 03080, Spain

[3] Univ Perugia, Dept Chem Biol & Biotechnol, Via Elce Sotto 8, I-06124 Perugia, Italy

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2021年 / 2021卷 / 29期

关键词：

Active solvents; Asymmetric organocatalysis; Deep eutectic solvents; Enantioselectivity; Green chemistry; CHIRAL IONIC LIQUIDS; 1,3-DICARBONYL COMPOUNDS; CONJUGATE ADDITION; MICHAEL ADDITION; REACTION MEDIA; MALEIMIDES; 2-AMINOBENZIMIDAZOLES; ALDEHYDES; MIXTURES;

D O I：

10.1002/ejoc.202100385

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The recent advances in asymmetric organocatalysis using eutectic mixtures as a reaction medium are revised in this mini-review. In addition, the first enantioselective transformations using chiral eutectic solvents, which play the role of a green medium and organocatalyst, are described. In this minireview we intend to deepen not only in the synthetic aspects of asymmetric organocatalysis in eutectic mixtures, but also in the fundamental issues that seem to be essential for a successful development of this promising, and at the same time challenging, methodology.

引用

页码：4065 / 4071

页数：7

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