SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURE OF Cd(II) COMPLEX WITH POTENTIALLY HEPTADENTATE SCHIFF BASE LIGAND

被引：0

作者：

Khojasteh, Roya Ranjineh ^{[1
]}

Matin, Sara Jalali ^{[1
]}

机构：

[1] Islamic Azad Univ, Tehran North Branch, Fac Chem, Dept Inorgan Chem, Tehran, Iran

来源：

REVUE ROUMAINE DE CHIMIE | 2016年 / 61卷 / 02期

关键词：

crystal structure; supramolecular structure; heptadentate ligand; cadmium (II) complex; tris(2-aminoethyl)amine;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The heptadentate N4O3-type Schiff base was derived from the condensation reaction of salicylaldehyde and tris(2-aminoethyl)amine. The heptadentate Schiff base ligand was characterized by elemental analysis, H-1-, C-13-NMR, IR and UV-VIS spectroscopy techniques. A novel Cadmium (II) complex was also synthesized. The complex was characterized by IR and UV-VIS spectra, and X-ray single crystal diffraction. X-ray structure analysis of the former complex shows mono-capped distorted trigonal antiprism geometry. The complex crystallizes in the monoclinic system with space group P2(1)/c. It is noteworthy that the tripodal heptadentate Schiff base ligand effectively encapsulates the Cadmium (II) ion and enforces seven-coordinate geometry in complex.

引用

页码：83 / +

页数：6

共 50 条

[1] Synthesis and Crystal Structure of a Co(II) Complex with Schiff Base and Imidazole Ligand
WU Lian-Bin HU Zi-Qiang LAI Guo-Qiao② (Key Laboratory of Organosilicon Chemistry and Material Technology of Education Ministry
Chinese Journal of Structural Chemistry, 2006, (05) : 567 - 571
[2] Synthesis and crystal structure of a Co(II) complex with Schiff base and imidazole ligand
Wu Lian-Bin
Hu Zi-Qiang
Lai Guo-Qiao
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 25 (05) : 567 - 571
[3] Synthesis and Crystal Structure of a Co(II) Complex with Schiff Base and Imidazole Ligand
WU LianBin HU ZiQiang LAI GuoQiao Key Laboratory of Organosilicon Chemistry and Material Technology of Education MinistryHangzhou Teachers University Hangzhou China
结构化学, 2006, (05) : 567 - 571
[4] Synthesis, characterization, crystal structure and DFT studies of a palladium(II) complex with an asymmetric Schiff base ligand
Kargar, Hadi
Torabi, Vajiheh
Akbari, Alireza
Behjatmanesh-Ardakani, Reza
Tahir, Muhammad Nawaz
JOURNAL OF MOLECULAR STRUCTURE, 2019, 1179 : 732 - 738
[5] Synthesis and crystal structure of a new Schiff base ligand and its cobalt(II) complex
Li, Y. G.
Dong, X. W.
Ai, R.
Xu, X. L.
Zhu, H. L.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2011, 37 (07) : 523 - 527
[6] Synthesis and crystal structure of a new Schiff base ligand and its cobalt(II) complex
Y. G. Li
X. W. Dong
R. Ai
X. L. Xu
H. L. Zhu
Russian Journal of Coordination Chemistry, 2011, 37 : 523 - 527
[7] Nickel(II) complex with an asymmetric tetradentate Schiff base ligand: synthesis, characterization, crystal structure, and DFT studies
Torabi, Vajiheh
Kargar, Hadi
Akbari, Alireza
Behjatmanesh-Ardakani, Reza
Rudbari, Hadi Amiri
Tahir, Muhammad Nawaz
JOURNAL OF COORDINATION CHEMISTRY, 2018, 71 (22) : 3748 - 3762
[8] Synthesis, crystal structure and characterization of a new mononuclear Zn(II) complex from Schiff-base ligand
Jun, Chen
Xu Xing-You
Jian, Gao
Li Yan-Hui
Xu Guo-Xiang
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 26 (06) : 632 - 636
[9] Synthesis and characterization of a thioether Schiff base ligand and its metal complexes and crystal structure determination of the nickel(II) complex
Dehghani-Firouzabadi, Ahmad Ali
Kargar, Hadi
Eslaminejad, Safie
Notash, Behrouz
JOURNAL OF COORDINATION CHEMISTRY, 2015, 68 (24) : 4345 - 4354
[10] Synthesis, characterization, and crystal structure of a novel trinuclear Schiff base nickel(II) complex
Cao, Guo-Biao
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2007, 37 (08) : 639 - 642

← 1 2 3 4 5 →