A New Method for Processing of Low-Grade Monazite Concentrates

It is very tedious to separate thorium and rare earth elements from their accompanying constituents in low-grade monazite (concentrate 50%) containing large amount of phosphorus species, illiminite, silica and zircon. Therefore, trials have been suggested to develop a new procedure to enhance the separation process of the light lanthanides from low-grade Egyptian monazite concentrates. The first point is focused on the removal of phosphorus species from the digested low-grade monazite with sulfuric acid in order to get more convenient separation. The removal was accomplished by extractive washing of sulfate paste with different alcohols. The results showed that the extractive removal of phosphorus species was not effective due to the complex nature of low-grade monazite concentrate. The second point is focused on the enhancement of separation process of uranium, thorium and rare earth elements by new ratio of sulfuric acid and develops the classical separation process. By this modified procedure, the overall results obtained revealed that the unleached residue contains mainly Si, Fe, Zr, and Ti while the elements of main consideration such as uranium, thorium and light rare earth elements were completely leached. Thorium and light rare earth elements (LREEs) were directly separated as white precipitate while the uranium was moved to the green acid solution with most of phosphorus species. This throws light on the possibility of separation of thorium and light rare earth elements from uranium, which represents a novel method.