Preparation and structure of double complex compounds [La(HMPA)4(NO3)2][Cr(NH3)2(NCS)4]

被引:4
|
作者
Bobrovnikova, A. A. [1 ]
Cherkasova, T. G. [1 ]
Shirokolobova, A. G. [1 ]
Bolsunovskaya, L. M. [2 ]
机构
[1] TF Gorbachev Kuzbass State Tech Univ, Kemerovo, Russia
[2] Natl Res Tomsk Polytech Univ, Tomsk, Russia
关键词
double complex salts (DCS); rare-earth elements (REEs); tetra(isotiocyanato)diaminechromates(III) ammonium; hexamethylphosphorotriamide (HMPA); X-ray structural analysis;
D O I
10.1016/j.proche.2014.10.090
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This paper presents the results of chemical analysis, IR-spectroscopic analysis, thermal gravitational analysis, X-ray phase analysis, and X-ray structural analysis, conducted to determine the composition, structure and properties of the double complex salts - tetra(isotiocyanato)diaminechromates(III) of complex lanthanon(III) of ceric group with hexamethylphosphorotriamide (HMPA) and nitrate-groups as ligands. (C) 2014 The Authors. Published by Elsevier B.V.
引用
收藏
页码:530 / 534
页数:5
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