Optical rotatory feature of (R or S)-1,1′-binaphthalene-2,2′-diol (BINOL) in various solvents

被引：0

作者：

Chen, CF ^{[1
]}

Li, Z ^{[1
]}

Ai, M ^{[1
]}

Chen, YM ^{[1
]}

Xi, F ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2003年 / 21卷 / 02期

关键词：

1; '-binaphthalene-2; 2; '-diol; solute-solvent interaction; specific rotation; cisoid and transoid conformation;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The changes of the specific rotation and sip of optically active BINOL have been studied in polar/non-polar solvents and at the different pH values of solvent. It is considered that these changes are determined by the equilibrium studies between cisoid and transoid conformations of BINOL with the same configuration ( R or S) which related to the change of the dihedral angle between two naphthalene ring planes of BINOL.

引用

页码：204 / 207

页数：4

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