Reliable and Diverse Synthesis of Aryl Azides through Copper-Catalyzed Coupling of Boronic Acids or Esters with TMSN3

被引：80
|
作者：
Li, Yu [1 ,2 ]
Gao, Lian-Xun [1 ]
Han, Fu-She [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Jilin, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100864, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 27期
关键词：
aryl azides; boronic acids; boronic esters; copper; cross-coupling; HUISGEN 1,3-DIPOLAR CYCLOADDITION; CLICK CHEMISTRY APPROACH; TETRAZOLE FORMATION; AROMATIC-AMINES; REACTIVITY; AZIRIDINES; CONVERSION; COMPLEXES; NITRILES; CYANIDES;
D O I：
10.1002/chem.201000971
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Aryl azide formation: The copper-catalyzed coupling reaction of boronic esters and acids with TMSN3 have been presented as a highly efficient, simple, broadly applicable, and less hazardous methodology for the practi cal synthesis of aryl azides with structural diversity (see scheme). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：7969 / 7972
页数：4
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