Metal π complexes of carbazole derivatives for optoelectronics:: Synthesis, structures, and UV-visible absorption spectra of (3-amino-9-ethylcarbazole)chromium tricarbonyl complexes

被引：17

作者：

Shen, KY

Tian, XH ^{[1
]}

Zhong, JH

Lin, JP

Shen, Y

Wu, PY

机构：

[1] E China Univ Sci & Technol, Sch Mat Sci & Engn, Shanghai 200237, Peoples R China

[2] Fudan Univ, Key Lab Mol Engn Polymers, Minist Educ, Shanghai 200433, Peoples R China

[3] E China Univ Sci & Technol, Dept Phys, Shanghai 200237, Peoples R China

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 01期

关键词：

D O I：

10.1021/om0495527

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chromium tricarbonyl. complexes eta(6)-bonded to 3-amino-9-ethylcarbazole at either the NH2-substituted aryl ring (1) or the unsubstituted aryl ring (2) have been synthesized and their UV-visible absorption spectra determined. In comparison to 2, 1 causes a subtle blue shift in the metal-to-ligand charge-transfer band along with spectral shape changes due to electron transfer from the NH2 substituent to the Cr(CO)(3) center.

引用

页码：127 / 131

页数：5

共 4 条

[1] Structural dependences of the η~6 complexes of 3-amino-9-ethylcarbazole with chromium tricarbonyl fragment on third-order optical nonlinearities
YUAN YiZhong1
2 School of Materials Science and Engineering
ChineseScienceBulletin, 2008, (10) : 1473 - 1478
[2] Structural dependences of the η6 complexes of 3-amino-9-ethylcarbazole with chromium tricarbonyl fragment on third-order optical nonlinearities
Yuan YiZhong
Sun ZhenRong
Wang ZuGeng
CHINESE SCIENCE BULLETIN, 2008, 53 (10): : 1473 - 1478
[3] Synthesis, structures, and UV-visible absorption spectra of tri(9-anthryl)bismuthine derivatives
Yamaguchi, S
Shirasaka, T
Tamao, K
ORGANOMETALLICS, 2002, 21 (12) : 2555 - 2558
[4] THE METAL-COMPLEXES OF HETEROCYCLIC BETA-DIKETONES AND THEIR DERIVATIVES .9. LANTHANON CHELATES OF 3-METHYL-1-PHENYL-4-TRIFLUOROACETYLPYRAZOL-5-ONE (HPMTFP) - H-1,C-13 AND F-19-NMR, IR AND UV-VISIBLE SPECTRAL STUDIES
OKAFOR, EC
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1982, 38 (09): : 981 - 987

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