Modeling of electrochemical processes in solid oxide fuel cells

被引：2
|
作者：
Averkov, I. S. [1 ]
Baykov, A. V. [1 ,2 ]
Yanovskiy, L. S. [1 ,2 ]
Volokhov, V. M. [2 ]
机构：
[1] PI Baranov Cent Inst Aviat Motors, 2 Ul Aviamotornaya, Moscow 111116, Russia
[2] Russian Acad Sci, Inst Problems Chem Phys, 1 Prosp Akad Semenova, Chernogolovka 142432, Moscow Region, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2016年 / 65卷 / 10期
基金：
俄罗斯科学基金会;
关键词：
electrochemistry; solid oxide fuel cells; thermodynamics; electromotive force;
D O I：
10.1007/s11172-016-1592-8
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A mathematical model of electrochemical processes in a solid oxide fuel cell is presented. A procedure for the calculation of the current-voltage characteristic (CVC) taking into account the influence of the reagent concentration, pressure, and temperature is considered. The problem of calculation of the electromotive force (emf) and thermodynamic efficiency was studied in detail. The influence of the presence of carbon dioxide and water vapor in the anode gas on the emf and thermodynamic efficiency is analyzed. The method of measuring the CVC in an experiment at a constant fuel rate is briefly considered. The results of application of the calculation model are compared with the experimental data.
引用
收藏
页码：2375 / 2380
页数：6
相关论文
共 50 条
  • [1] Modeling of electrochemical processes in solid oxide fuel cells
    I. S. Averkov
    A. V. Baykov
    L. S. Yanovskiy
    V. M. Volokhov
    [J]. Russian Chemical Bulletin, 2016, 65 : 2375 - 2380
  • [2] Numerical Simulation of Electrochemical and Transport Processes in Solid Oxide Fuel Cells
    Ho, T. X.
    Kosinski, P.
    Hoffmann, A. C.
    Waernhus, I.
    Vik, A.
    [J]. SOLID OXIDE FUEL CELLS 10 (SOFC-X), PTS 1 AND 2, 2007, 7 (01): : 1901 - +
  • [3] Connecting microstructural coarsening processes to electrochemical performance in solid oxide fuel cells: An integrated modeling approach
    Abdeljawad, Fadi
    Voelker, Benjamin
    Davis, Ryan
    McMeeking, Robert M.
    Haataja, Mikko
    [J]. JOURNAL OF POWER SOURCES, 2014, 250 : 319 - 331
  • [4] Computational modeling of the transport and electrochemical phenomena in solid oxide fuel cells
    Mahcene, Hocine
    Ben Moussa, Hocine
    Bouguettaia, Hamza
    Bechki, Djamel
    Zeroual, Mostefa
    [J]. IMPACT OF INTEGRATED CLEAN ENERGY ON THE FUTURE OF THE MEDITERRANEAN ENVIRONMENT, 2011, 6 : 65 - 74
  • [5] Modeling of solid oxide fuel cells
    Meng Ni
    [J]. Science Bulletin, 2016, 61 (17) : 1311 - 1312
  • [6] Modeling of solid oxide fuel cells
    Ni, Meng
    [J]. SCIENCE BULLETIN, 2016, 61 (17) : 1311 - 1312
  • [7] Numerical Modeling of Physical Property and Electrochemical Reaction for Solid Oxide Fuel Cells
    Park, Joonguen
    Kim, Sunyoung
    Bae, Joongmyeon
    [J]. TRANSACTIONS OF THE KOREAN SOCIETY OF MECHANICAL ENGINEERS B, 2010, 34 (02) : 157 - 163
  • [8] Electrochemical modeling and parametric study of methane fed solid oxide fuel cells
    Ni, Meng
    Leung, Dennis Y. C.
    Leung, Michael K. H.
    [J]. ENERGY CONVERSION AND MANAGEMENT, 2009, 50 (02) : 268 - 278
  • [9] Electrochemical Simulation of Planar Solid Oxide Fuel Cells with Detailed Microstructural Modeling
    Bertei, A.
    Mertens, J.
    Nicolella, C.
    [J]. ELECTROCHIMICA ACTA, 2014, 146 : 151 - 163
  • [10] Electrode processes in solid oxide fuel cells
    Riess, I
    [J]. OXYGEN ION AND MIXED CONDUCTORS AND THEIR TECHNOLOGICAL APPLICATIONS, 2000, 368 : 21 - 56
12345