Modified Julia-Kocienski Reaction Promoted by Means of m-NPT (Nitrophenyltetrazole) Sulfone

被引：10
|
作者：
Sakai, Yuki
Ikeuchi, Kazutada
Yamada, Yuji
Wakimoto, Toshiyuki
Kan, Toshiyuki [1 ]
机构：
[1] Univ Shizuoka, Sch Pharmaceut Sci, Suruga Ku, Shizuoka 4228526, Japan
来源：
SYNLETT | 2010年 / 05期
关键词：
olefination; Julia-Kocienski reaction; sulfone; STEREOSELECTIVE-SYNTHESIS; CONDENSATION; ALDEHYDES;
D O I：
10.1055/s-0029-1219386
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
m-Nitrophenyltetrazole sulfone (2) was employed in the Julia-Kocienski reaction. The olefination reaction between 2 and carbonyl compounds proceeded smoothly under Masamune-Roush conditions (DBU and LiCl). These conditions were also applicable to our catechin derivative synthesis. Furthermore, phenolic mesylate was also tolerated in this mild reaction.
引用
收藏
页码：827 / 829
页数：3
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