Novel polymer supported vanadium (V) and chromium (VI) ions as oxidation catalysts

被引：0
|
作者：
Suresh, S [1 ]
Skaria, S [1 ]
Ponrathnam, S [1 ]
机构：
[1] Natl Chem Lab, Div Chem Engn, Polymer Sci & Engn Grp, Pune 411008, Maharashtra, India
来源：
RECENT ADVANCES IN BASIC AND APPLIED ASPECTS OF INDUSTRIAL CATALYSIS | 1998年 / 113卷
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D O I：
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中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Macroporous glycidyl methacrylate-ethylene glycol dimethacrylate (GMA-EGDM) copolymer beads were synthesised and characterised for pore volume and surface area. These reactive copolymers were derivatised with 2-picolyl amine and coordinated with chromium and vanadium ions. The peroxocomplexes of these supported metal complexes were generated by the addition of hydrogen peroxide / tertiary butyl hydroperoxide(tert.- BHP) and shown to catalyse a variety of oxidation reactions.
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页码：915 / 919
页数：5
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