Synthesis and properties of novel star-shaped oligofluorene conjugated systems with BODIPY cores

被引:8
|
作者
Orofino-Pena, Clara [1 ]
Cortizo-Lacalle, Diego [1 ]
Cameron, Joseph [1 ]
Sajjad, Muhammad T. [2 ]
Manousiadis, Pavlos P. [2 ]
Findlay, Neil J. [1 ]
Kanibolotsky, L. [1 ,3 ]
Amarasinghe, Dimali [2 ]
Skabara, Peter J. [1 ]
Tuttle, Tell [1 ]
Turnbull, Graham A. [2 ]
Samuel, Ifor D. W. [2 ]
机构
[1] Univ Strathclyde, WestCHEM, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland
[2] Univ St Andrews, Sch Phys & Astron, Organ Semicond Ctr, SUPA, St Andrews, NB KY16 9SS, Canada
[3] Inst Phys Organ Chem & Coal Chem, UA-83114 Donetsk, Ukraine
来源
基金
英国工程与自然科学研究理事会;
关键词
absorption spectroscopy; BODIPY; cyclic voltammetry; photoluminescence; star-shaped oligofluorene; ELECTROCHEMICAL PROPERTIES; MULTICHROMOPHORIC ARRAYS; COUPLING REACTIONS; DYES; DERIVATIVES; CHEMISTRY; DESIGN; RED;
D O I
10.3762/bjoc.10.285
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Star-shaped conjugated systems with varying oligofluorene arm length and substitution patterns of the central BODIPY core have been synthesised, leading to two families of compounds, T-B1-T-B4 and Y-B1-Y-B4, with T- and Y-shaped motifs, respectively. Thermal stability, cyclic voltammetry, absorption and photoluminescence spectroscopy of each member of these two families were studied in order to determine their suitability as emissive materials in photonic applications.
引用
收藏
页码:2704 / 2714
页数:11
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