Synthesis and structure of a novel binuclear rhenium(I) complex containing an unusual bridging ligand derived from coordinated acetonitrile.: Unusual reactivity of [Re(CO)3(bpy)(MeCN)]+

被引：10

作者：

Yam, VWW ^{[1
]}

Wong, KMC ^{[1
]}

Cheung, KK ^{[1
]}

机构：

[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 01期

关键词：

D O I：

10.1039/a707514f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Re(CO)(3)(bpy)(MeCN)](+) forms a novel binuclear rhenium(I) complex containing a N=CCH=C(CH3)NH bridge derived from the reaction of the coordinated acetonitrile with NaH; the crystal structure of which has been determined.

引用

页码：135 / 136

页数：2

共 21 条

[1] SYNTHESIS AND STRUCTURE OF DINUCLEAR NIOBIUM AND TANTALUM COMPLEXES CONTAINING AN UNUSUAL BRIDGING LIGAND DERIVED FROM ACETONITRILE
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[2] Synthesis, photophysics, and electrochemistry of luminescent binuclear rhenium(I) complexes containing mu-bridging thiolates. X-ray crystal structure of [{Re(bpy)(CO)(3)}(2)(mu-SC6H4-CH3-p)]OTf
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ORGANOMETALLICS, 1997, 16 (08) : 1729 - 1734
[3] CLUSTERS CONTAINING CARBENE LIGANDS - THE UNUSUAL SYNTHESIS, COORDINATION, AND REACTIVITY OF A BRIDGING (DIMETALLIOMETHYL)(DIETHYLAMINO)CARBENE LIGAND IN THE CLUSTER COMPLEX OS3(CO)9[MU-3-HCC(NET2)](MU-H)2
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[5] THE SYNTHESIS OF CIS-RE(O,O'-NO2)(CO)2(PPH3)2 CONTAINING THE UNUSUAL O,O'-CHELATING NITRITE LIGAND AND ITS REACTION WITH CO - EVIDENCE FOR A RHENIUM-NITROGEN INTERACTION
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JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 371 (03) : 321 - 328
[6] Easy elimination of bridging water molecule from a binuclear cobalt(II) complex.: Synthesis and structure of the [Co2(μ-OOCBut)2(PirH)4(MeCN)2][OS(O)2CF3]2 complex (PirH is 3,5-dimethylpyrazole)
Denisova, TO
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RUSSIAN CHEMICAL BULLETIN, 2003, 52 (04) : 1035 - 1037
[7] Easy elimination of bridging water molecule from a binuclear cobalt(ii) complex. Synthesis and structure of the [Co2(μ-OOCBut)2(PirH)4(MeCN)2][OS(O)2CF3]2 complex (PirH is 3,5-dimethylpyrazole)
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S. E. Nefedov
Russian Chemical Bulletin, 2003, 52 : 1035 - 1037
[8] A dinuclear bis(bipyridine)ruthenium(II) complex, [(bpy)2RuII{L2-}RuII(bpy)2]2+, incorporating an unusual non-innocent bridging ligand containing a p-benzoquinonediimine fragment:: synthesis, structure, redox, and UV/VIS/NIR and EPR spectroelectrochemical properties
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JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (06): : 1172 - 1179
[9] PREPARATION AND STRUCTURE OF W(CO)5OPPH2NPPH3, A NOVEL COMPLEX CONTAINING A LIGAND DERIVED FROM THE "BIS(TRIPHENYLPHOSPHINE)NITROGEN(1+) CATION
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[10] AN UNUSUAL COMPLEX DERIVED FROM MOCL3(THF)3 AND AGBF4 IN ACETONITRILE - SYNTHESIS AND STRUCTURE OF [MO2(MU-F)(NCCH3)8O2][BF4]3
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