Photoisomerisation and light-induced morphological switching of a polyoxometalate-azobenzene hybrid

被引：19
|
作者：
Markiewicz, Grzegorz [1 ,2 ]
Pakulski, Dawid [1 ,3 ]
Galanti, Agostino [3 ]
Patroniak, Violetta [1 ]
Ciesielski, Artur [3 ]
Stefankiewicz, Artur R. [1 ,2 ]
Samori, Paolo [3 ]
机构：
[1] Adam Mickiewicz Univ, Fac Chem, Umultowska 89b, PL-61614 Poznan, Poland
[2] Adam Mickiewicz Univ, Ctr Adv Technol, Umultowska 89c, PL-61614 Poznan, Poland
[3] Univ Strasbourg, CNRS, ISIS, 8 Allee Gaspard Monge, F-67000 Strasbourg, France
来源：
CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 53期
关键词：
SURFACTANT; COMPLEX; CATALYSIS; FUNCTIONALIZATION; NANOPARTICLES; ASSEMBLIES; MOLECULES; DESIGN;
D O I：
10.1039/c7cc01805c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The functionalization of a spherical Keplerate-type polyoxometalate {Mo72V30} with a cationic azobenzene surfactant has been achieved through ionic self-assembly. The photoisomerisation reaction of this complex, which emerges in a light-triggered aggregation-disaggregation process, has been followed by H-1 NMR spectroscopy, dynamic light scattering, absorption spectroscopy and scanning electron microscopy analyses.
引用
收藏
页码：7278 / 7281
页数：4
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