Triterpene glycosides from Pulsatilla chinensis

被引:23
|
作者
Glebko, LI [1 ]
Krasovskaj, NP [1 ]
Strigina, LI [1 ]
Ulanova, KP [1 ]
Denisenko, VA [1 ]
Dmitrenok, PS [1 ]
机构
[1] Russian Acad Sci, Pacific Inst Bioorgan Chem, Vladivostok 690022, Russia
关键词
Pulsatilla chinensis; Ranunculaceae; triterpene glycosides; glycosides of 23-hydroxybetulinic acid; chinensiosides A and B; H-1 and C-13 NMR spectra; MALDI-TOF mass spectra;
D O I
10.1023/A:1021381308598
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Four triterpene glycosides were isolated from the roots of Pulsatilla chinensis (Bunge) Regel (Ranunculaceae). Two new glycosides, chinensiosides A (1a) and B (2), were identified as 3-O-[alpha-L-rhamnopyranosyl-(1-->2)-alpha-L-arabinopyranosyl]-28-O-[alpha-L-rhamnopyranosyl-(1-->4)-beta-D-glucopyranosyl-(1-->6)-beta-D-glucopyranosyl]-3beta,23-dihydroxylup-20(29)-en-28-oic acid and 3-O-[alpha-L-rhamnopyranosyl-(1-->2)-[beta-D-glucopyranosyl-(1-->4)-alpha-L-arabinopyranosyl]-28-O-[alpha-L-rhamnopyranosyl-(1-->4)-beta-D-glucopyranosyl-(1-->6)-beta-D-glucopyranosyl]-3beta,23-dihydroxylup-20(29)-en-28-oic acid. The other two glycosides were identified as previously known hederasaponin C (3) from Hedera helix and glycoside III (4) from Pulsatilla cernua.
引用
收藏
页码:1945 / 1950
页数:6
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