Making and breaking of Zn-C bonds in the cases of allyl and propargyl organozincs

被引：3
|
作者：
Mondal, Bibhas [1 ,2 ]
Roy, Ujjal Kanti [1 ]
机构：
[1] Kazi Nazrul Univ, Dept Chem, Asansol 713340, W Bengal, India
[2] Natl Inst Technol Durgapur, Dept Chem, Durgapur 713209, India
来源：
TETRAHEDRON | 2021年 / 90卷
关键词：
Organozinc; Allylzinc; Propargylzinc; Aldehyde; Ketone; Imine; ZINC-MEDIATED ALLYLATION; BARBIER-TYPE ALLYLATION; HIGHLY EFFICIENT SYNTHESIS; CARBONYL-COMPOUNDS; AQUEOUS-MEDIA; STEREOSELECTIVE-SYNTHESIS; ORGANOMETALLIC REACTIONS; HOMOALLYLIC ALCOHOLS; ALLENYLZINC REAGENTS; IN-SITU;
D O I：
10.1016/j.tet.2021.132169
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This review aims to sum up recent developments in the synthesis of homoallylic and homopropargylic alcohols or amines by using methods based on catalytic or stoichiometric use of metallic zinc for allylation and propargylations of carbonyls or imines. These methods encompass various transformations which are now commonly expressed as Barbier-Grignard type reactions including several chemical or electrochemical processes. (C) 2021 Elsevier Ltd. All rights reserved.
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页数：26
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