Synthesis, crystal structure, and thermal properties of [Pd(NH3)4][AuCl4]2

被引：20
|
作者：
Plyusnin, P. E. [1 ]
Baidina, I. A. [1 ]
Shubin, Yu. V. [1 ]
Korenev, S. V. [1 ]
机构：
[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 52卷 / 03期
关键词：
Complexation - Crystal structure - Raman spectroscopy - Synthesis (chemical) - Thermodynamic properties - X ray diffraction;
D O I：
10.1134/S0036023607030138
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The double complex salt [Pd(NH3)(4)][AuCl4](2) was synthesized and studied by X-ray diffraction: a = 7.5234(6) angstrom, b = 7.7909(5) angstrom, c = 8.0247(6) angstrom, alpha = 108.483(2)degrees, beta = 106.497(2)angstrom, gamma = 99.972(3)angstrom, V = 409.43(5) angstrom(3), space group P (1) over bar, Z = 1, rho(calod) = 3.456 g/cm(3), R = 0.0267. The compound was characterized by powder X-ray diffraction, thermal analysis, and IR and Raman spectroscopy. The metal products of thermolysis of the complex were studied by powder X-ray diffraction.
引用
收藏
页码：371 / 377
页数：7
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