Synthesis, NMR spectroscopy, and conformational analysis of α-dimethylsilyl esters

被引：3
|
作者：
Kaimakliotis, C [1 ]
Arthanari, H [1 ]
Fry, AJ [1 ]
机构：
[1] Wesleyan Univ, Dept Chem, Hall Atwater Lab, Middletown, CT 06459 USA
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 671卷 / 1-2期
关键词：
Si-29-NMR spectroscopy; conformational analysis; alpha-dimethylsilyl esters;
D O I：
10.1016/S0022-328X(03)00073-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The conformational properties of alpha-dimethylsilyl esters, synthesized in excellent yields by reaction of ester enolates with chlorodimethylsilane (DMSCl), have been explored by both molecular mechanics calculations and a variety of H-1- and Si-29-NMR spectroscopic experiments. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：126 / 130
页数：5
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