Copper Mixed Valence Concept: "Cu(I)-Cu(II)" in Thermoelectric Copper Sulfides-an Alternative to "Cu(II)-Cu(III)" in Superconducting Cuprates

被引：16

作者：

Raveau, Bernard ^{[1
]}

机构：

[1] Univ Caen, CNRS, ENSICAEN, UMR 6508, 6 Bd Marechal Juin, F-14050 Caen, France

来源：

JOURNAL OF SUPERCONDUCTIVITY AND NOVEL MAGNETISM | 2020年 / 33卷 / 01期

关键词：

Copper mixed valence; Cu-based metallic conductors; Thermoelectric sulfides; Superconducting cuprates; PERFORMANCE; TA; NB;

D O I：

10.1007/s10948-019-05354-8

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

The present essay is focused on the role of the Cu(I)-Cu(II) mixed valence for designing thermoelectric sulfides with p-type metal-like properties. A comparison is made with the concept of Cu(II)-Cu(III) mixed valence used for the synthesis of high Tc superconducting cuprates. Attention is drawn on the structural and metal-like conductivity analogy of these thermoelectric sulfides with CuCl, which was previously investigated as a potential superconductor by T. Geballe et al.

引用

页码：259 / 263

页数：5

共 50 条

[1] Copper Mixed Valence Concept: “Cu(I)–Cu(II)” in Thermoelectric Copper Sulfides—an Alternative to “Cu(II)–Cu(III)” in Superconducting Cuprates
Bernard Raveau
[J]. Journal of Superconductivity and Novel Magnetism, 2020, 33 : 259 - 263
[2] DETERMINATION OF CU(III) AND CU(II)+CU(III) IN SUPERCONDUCTING COPPER CERAMICS
NEDELCHEVA, T
STOYANOVAIVANOVA, A
KOSTADINOVA, L
IVANOVA, I
[J]. FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1992, 342 (1-2): : 196 - 198
[3] HIGHLY DELOCALIZED CU(I)/CU(II) - A COPPER COPPER BOND
HARDING, C
MCKEE, V
NELSON, J
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (25) : 9684 - 9685
[4] IDENTIFICATION OF CU(II)/CU(III) COUPLES IN BINUCLEAR COPPER(II) COMPLEXES
ZACHARIAS, PS
RAMACHANDRAIAH, A
[J]. POLYHEDRON, 1985, 4 (06) : 1013 - 1017
[5] DEFORMATIONS IN MIXED-VALENCE CU(I)-CU(II) POLYMERS
SHERWOOD, P
HOFFMANN, R
[J]. INORGANIC CHEMISTRY, 1989, 28 (03) : 509 - 518
[6] INTERACTION OF COPPER WITH HISTIDINE AND TIME-DEPENDENT FORMATION OF A MIXED-VALENCE CU(I)-CU(II) POLYMER
WALKER, WR
REEVES, RR
LI, NC
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1975, (169): : 134 - 134
[7] An investigation of the reaction of copper ions with dimethylindodicarbocyanine dye An application for the determination of Cu(I), Cu(II) and Cu(III)
Balogh, Ioseph S.
Ruschak, Michael
Andruch, Vasil
Bazel, Yaroslav
[J]. TALANTA, 2008, 76 (01) : 111 - 115
[8] NITRITE COORDINATION TO COPPER(I), DICOPPER(I), AND MIXED-VALENCE CU(I)/CU(II) COMPLEXES - MODELING NITRITE BINDING TO COPPER SITES IN PROTEINS
HALFEN, JA
MAHAPATRA, S
TOLMAN, WB
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 239 - INOR
[9] Synthesis and Characterization of Cu(II) and Mixed-Valence Cu(I)Cu(II) Clusters Supported by Pyridylamide Ligands
Schneider, Joseph D.
Smith, Brett A.
Williams, Grant A.
Powell, Douglas R.
Perez, Felio
Rowe, Gerard T.
Yang, Lei
[J]. INORGANIC CHEMISTRY, 2020, 59 (08) : 5433 - 5446
[10] Perturbation of the electronic structure of a copper(II) ion by a Cu(I)Cl moiety in a class I mixed valence copper complex, Cu-II(Me(5)dien)Cl-2(Cu(I)Cl)
Breeze, SR
Wang, SN
[J]. INORGANIC CHEMISTRY, 1996, 35 (11) : 3404 - 3408

← 1 2 3 4 5 →