Thermal isomerization of α-pinene in supercritical ethanol

被引：17
|
作者：
Yermakova, A.
Chibiryaev, A. M.
Kozhevnikov, I. V.
Mikenin, P. E.
Anikeev, V. I.
机构：
[1] Russian Acad Sci, SB, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
[2] Russian Acad Sci, SB, Novosibirsk Organ Chem Inst, Novosibirsk 630090, Russia
来源：
CHEMICAL ENGINEERING SCIENCE | 2007年 / 62卷 / 09期
关键词：
supercritical solvents-fluids terpene compounds; alpha-pinene; kinetic model; model identification; pressure effect; transition state;
D O I：
10.1016/j.ces.2007.01.041
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The experimental study followed by mathematical processing of the data showed that supercritical ethanol is an effective reaction medium for thermal isomerization of alpha-pinene. Rate of the reaction in supercritical solvent is by several orders of magnitude greater than the rate observed under normal conditions, with selectivity to the target reaction products being retained. The study allowed us for the first time to obtain the kinetic model of alpha-pinene isomerization in supercritical ethanol that takes into account temperature and pressure effect on the reaction rate and selectivity. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2414 / 2421
页数：8
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