Synthesis and crystal structure of fluorine-containing α-aminophosphonates

被引：0

作者：

Yang, S ^{[1
]}

Song, BA ^{[1
]}

Wu, YL ^{[1
]}

Jin, LH ^{[1
]}

Liu, G ^{[1
]}

Hiu, DY ^{[1
]}

Lu, P ^{[1
]}

机构：

[1] Guizhou Univ, Minist Educ, Res & Dev Ctr Fine Chem, Key Lab Green Pesticide & Agr Biol Engn, Guiyang 550025, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 24卷 / 10期

关键词：

alpha-aminophosphonate; synthesis; crystal structure;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two fluorine-containing alpha-aminophosphonate compounds were synthesized by the reaction of phenyl-imines with phosphite ester, and characterized by elemental analysis, H-1 NMR, FT-IR and MS spectra. X-ray single crystal diffraction analysis indicates that the crystal belongs to triclinic system with space group P-1, a = 1.0178(6) nm, b = 1.0354(6) nm, c = 2.2534(13) nm, alpha = 77.413(10)degrees, beta = 78.340(10)degrees, gamma = 77.540(10)degrees, V = 2.233(2) nm(3), Z = 4, D-e = 1.289 Mg.m(-3), mu = 0.175 mm(-1), F (000) = 840. The final R = 0.0728, wR = 0.1724.

引用

页码：1292 / 1295

页数：4

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