Complete vibrational spectrum of NiCO isolated in solid argon

被引：44

作者：

Joly, HA

Manceron, L ^{[1
]}

机构：

[1] Univ Paris 06, CNRS, URA 508, Lab Spectrochim Mol, F-75252 Paris 05, France

[2] Laurentian Univ, Dept Chem & Biochem, Sudbury, ON P3E 2C6, Canada

来源：

CHEMICAL PHYSICS | 1998年 / 226卷 / 1-2期

关键词：

D O I：

10.1016/S0301-0104(97)00312-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The infrared spectrum of NiCO isolated in solid argon has been reinvestigated. Isotopic data on nu(1), nu(2), nu(3), 2 nu(1), nu(1), nu(2) and nu(1) + nu(3) have been measured in the near-and far-infrared regions. This enables a complete harmonic force-field calculation based on the assumption of a linear geometry. Comparisons with bond force constants of Ni(CO)(4) and the latest ab initio predictions of the NiCO vibrational frequencies are also presented. (C) 1998 Elsevier Science B.V.

引用

页码：61 / 70

页数：10

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