Investigation of copper halide:: Hydrothermal syntheses and characterization of CuBr2(C12H8N2) and Cu3Br3(C12H8N2)2

被引：0
|
作者：
Zhao, XL
Xu, JQ [1 ]
Zhang, LJ
Yu, JH
Zeng, QX
Cui, XB
Wang, TG
Wang, TW
机构：
[1] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China
[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2003年 / 21卷 / 03期
关键词：
copper halide; crystal structure; hydrothermal synthesis;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of CuBr2 with 1, 10-phen-H2O (1, 10-phen = 1, 10-phenanthroline) gave two compounds: CuBr2(C12H8N2) Cu3Br3(C12H8N2)(2). Their Structures have been characterized by single-crystal X-ray diffraction analysis, elemental analyses, thermogravimetric analyses (TGA) and measurement of variable tem. perature magnetic susceptibility. Crystal data for CuBr2 (C-12-H8N2): monodinic, space group P2(1) / n, a = 0.9977(3) nm, b = 0.65138(14) mn, c = 1.8207 (4) mn, beta = 91.624 (18)degrees, V = 1.1828(5) mm(3), Z = 2. Crystal data for Cu3Br3 (C12H8N2)(2): monoclinic, space group C2/c, a = 1.00167(11) nm, b = 1.4523(4) run, c = 1.6295(3) nm, P = 94-386(14)degrees, V = 2.3635(8) mm(3), Z = 3.
引用
收藏
页码：296 / 300
页数：5
相关论文
共 50 条
  • [1] Hydrothermal syntheses and structural characterization of one-dimensional [Cu4Br2I3(C12H8N2)2]n and molecular Cu3Br3(C12H8N2)2
    Yu, JH
    Xu, JQ
    Ye, L
    Ding, H
    Xu, JN
    Jia, HB
    Wang, TG
    Mu, ZC
    Yang, GD
    JOURNAL OF CLUSTER SCIENCE, 2003, 14 (01) : 1 - 8
  • [2] Hydrothermal Syntheses and Structural Characterization of One-Dimensional [Cu4Br2I3(C12H8N2)2]n and Molecular Cu3Br3(C12H8N2)2
    Jie-Hui Yu
    Ji-Qing Xu
    Ling Ye
    Hong Ding
    Jia-Ning Xu
    Hong-Bin Jia
    Tie-Gang Wang
    Zhong-Cheng Mu
    Guang-Di Yang
    Journal of Cluster Science, 2003, 14 : 1 - 8
  • [3] Hydrothermal synthesis and crystal structure of Cu3I3(C12H8N2)2
    Yu, JH
    Shi, Z
    Xu, JQ
    Chu, DQ
    Jin, WJ
    Ding, H
    Hua, J
    Xu, JN
    Cui, XB
    Wang, TG
    Zhang, LJ
    Li, CB
    Zeng, QX
    POLISH JOURNAL OF CHEMISTRY, 2001, 75 (11) : 1785 - 1789
  • [4] COMPLEXES OF (PHENAZINE)-. AND (PHENAZINE)2- WITH MAGNESIUM(II) SYNTHESES OF [MG(C12H8N2)2(TETRAHYDROFURAN)3], [MG(C12H8N2)(TETRAHYDROFURAN)2], AND [MG2BR2(C12H8N2)(TETRAHYDROFURAN)6].[MGBR2(THF)4] (X-RAY AUTHENTICATED)
    JUNK, PC
    RASTON, CL
    SKELTON, BW
    WHITE, AH
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (15) : 1162 - 1164
  • [5] Thermal decomposition of Pr[（C5H8NS2）3(C12H8N2)]
    GUO Pengjiang
    Shaanxi Key Laboratory of Physico-lnorganic Chemistry
    Department of Mathematics
    Xi’an Modern Chemistry Research Institute
    Science China Chemistry, 2005, (S1) : 83 - 87
  • [6] Thermal decomposition of Pr[(C5H8NS2)3(C12H8N2)]
    Guo, PJ
    Jiao, BJ
    Chen, SP
    Hu, RZ
    Gao, SL
    Shi, QZ
    SCIENCE IN CHINA SERIES B-CHEMISTRY, 2005, 48 (Suppl 1): : 83 - 87
  • [7] Synthesis and characterization of complex Eu (C8H7O3)3 • C12H8N2 • H2O
    Wang, ST
    Yang, YL
    Li, X
    SPECTROSCOPY AND SPECTRAL ANALYSIS, 2000, 20 (03) : 324 - 325
  • [8] Synthesis and characterization of complex Eu (C8H7O3)3·C12H8N2·H2O
    Wang, Shaoting
    Yang, Yongli
    Li, Xia
    Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis, 2000, 20 (03): : 324 - 325
  • [9] Thermokinetics on the reaction of formation of Dy[（C5H8NS2）3(C12H8N2)]
    GAO Shengli
    Science China Chemistry, 2005, (S1) : 74 - 78
  • [10] Thermokinetics on the reaction of formation of Dy[(C5H8NS2)3(C12H8N2)]
    Gao, SL
    Chen, SP
    Jiao, BJ
    Shuai, Q
    Shi, QZ
    SCIENCE IN CHINA SERIES B-CHEMISTRY, 2005, 48 (Suppl 1): : 74 - 78
12345