Hexagonal layered materials composed of [M2(O2CCF3)4] (M = Ru and Rh) donors and TCNQ acceptors

被引：0
|
作者：
Miyasaka, H [1 ]
Campos-Fernández, CS [1 ]
Clérac, R [1 ]
Dunbar, KR [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2000年 / 39卷 / 21期
关键词：
D O I：
10.1002/1521-3773(20001103)39:21<3831::AID-ANIE3831>3.0.CO;2-D
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Delocalization throughout the extended layers of two-dimensional network polymers of the type [{M2(O2CCF3)4}2(TCNQ)·3(C7H8)]∞, which consist of Ru(II), Ru(II) and Rh(II), Rh(II) complexes coordinated to TCNQ molecules, is evident from the available structural (see picture for Ru analogue) and spectroscopic data. TCNQ = 7, 7, 8, 8-tetracyano-p-quinodimethane.
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页码：3831 / +
页数：6
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