(R)-1-Phenylethylammonium 6-amino-5-nitropyrimidine-2,4(1H,3H)-dionate (R)-1-phenylethylamine hemisolvate:: hydrogen-bonded sheets of ions with pendent solvent molecules

被引：1

作者：

Glidewell, C ^{[1
]}

Low, JN

Melguizo, M

Quesada, A

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] Univ Aberdeen, Dept Chem, Old Aberdeen AB24 3UE, Scotland

[3] Univ Jaen, Dept Quim Inorgan & Organ, Jaen 23071, Spain

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2003年 / 59卷

关键词：

D O I：

10.1107/S0108270103006383

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title compound, 2C(8)H(12)N(+).2C(4)H(3)N4O(4).C8H11N, the anions are linked by paired N - H...N hydrogen bonds [H...N = 2.07 and 2.11 Angstrom, N...N = 2.942 (3) and 2.978 (3) Angstrom and N - H...N = 173 and 170degrees] and by paired N - H...O hydrogen bonds [ H...O = 1.98 and 2.05 Angstrom, N...O = 2.855 ( 3) and 2.917 (3) Angstrom, and N - H...O = 173 and 167 degrees] into chains of rings. These chains are linked into sheets by further N - H...O hydrogen bonds in which all of the donors are provided by the cations [H...O = 1.83 - 2.17 A, N...O = 2.747 (3) - 2.965 (3) Angstrom and N - H...O = 141 - 168degrees]. The neutral amine molecule is pendent from the sheet and is linked to it by a single N-H...N hydrogen bond [ H...N = 2.00 Angstrom, N...N = 2.901 (3) Angstrom and N - H...N = 175 degrees].

引用

页码：O240 / O243

页数：4

共 50 条

[1] 6-Amino-3-methyl-5-nitrosopyrimidine-2,4(1H,3H)-dione forms a three-dimensional hydrogen-bonded framework structure
Salido, MLG
Valero, MDG
Low, JN
Glidewell, C
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2003, 59 (06): : O340 - O342
[2] Synthesis of 5-amino-6-nitrozopyrimidine-2,4(1H,3H)-dione
A. A. Yavolovskii
Yu. E. Ivanov
Russian Journal of General Chemistry, 2007, 77 : 1980 - 1980
[3] Synthesis of 5-amino-6-nitrozopyrimidine-2,4(1H,3H)-dione
Yavolovskii, A. A.
Ivanov, Yu. E.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2007, 77 (11) : 1980 - 1980
[4] 3-AMINO-6-BROMO-1-METHYL-2,4(1H,3H)-QUINAZOLINEDIONE
ARDEBILI, MHP
WHITE, JG
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (SEP): : 2890 - 2891
[5] Barium bis[6-amino-3-methyl-5-nitrosopyrimidine-2,4(1H,3H)-dionate] trihydrate:: coordination polymer chains linked by hydrogen bonds
Garzón, RL
Salido, MLG
Low, JN
Glidewell, C
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2003, 59 : M255 - M258
[6] Supramolecular structures of five 5-(arylmethylene)-1,3-dimethylpyrimidine-2,4,6(1H,3H,5H)-triones:: isolated molecules, hydrogen-bonded chains and chains of fused hydrogen-bonded rings
Rezende, MC
Dominguez, M
Wardell, JL
Skakle, JMS
Low, JN
Glidewell, C
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2005, 61 : O306 - O311
[7] 6-isopropoxy-5-isopropylpyrimidine-2,4(1H,3H)-dione
Lewis, W
McKeown, RH
Robinson, WT
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : O2429 - O2431
[8] A hydrogen-bonded ribbon in 6-amino-3-methyl-5-nitroso-2-(pyrrolidin-1-yl)pyrimidin-4(3H)-one monohydrate and hydrogen-bonded sheets in 6-amino-2-dimethylamino-3-methyl-5-nitrosopyrimidin-4(3H)-one monohydrate
Orozco, Fabian
Insuasty, Braulio
Cobo, Justo
Glidewell, Christopher
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2009, 65 : O549 - O552
[9] Bis[6-amino-3-methyl-5-nitrosopyrimidine-2,4(1H,3H)-dionato]diapuazinc(II) dihydrate, redetermined at 120 K:: a three-dimensional hydrogen-bonded framework
Garzón, RL
Salido, MLG
Low, JN
Glidewell, C
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2003, 59 : M291 - M293
[10] 2-Amino-3-methyl-6-[methyl(phenyl)amino]-5-nitropyrimidin-4 (3H)-one: polarized molecules within hydrogen-bonded sheets
Rodriguez, Ricaurte
Nogueras, Manuel
Cobo, Justo
Glidewell, Christopher
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2009, 65 : O441 - O443

← 1 2 3 4 5 →