Synthesis and crystal structures of two nickel coordination polymers generated from asymmetric malate ligand

被引：9

作者：

Guo, YQ ^{[1
]}

Xiao, DR ^{[1
]}

Wang, EB ^{[1
]}

Lu, Y ^{[1
]}

Lü, J ^{[1
]}

Xu, XX ^{[1
]}

Xu, L ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2005年 / 178卷 / 03期

基金：

中国国家自然科学基金;

关键词：

hydrothermally synthesized; cavities; crystal structures; malate; diamond-like; magnetic;

D O I：

10.1016/j.jssc.2004.12.042

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two nickel coordination polymers [Ni(H2O)(C4H4O5)] center dot H2O 1 and [Ni(H2O)(mal)(phen)] 2, have been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. Crystal data for 1: C4H8O7Ni, monoclinic Cc, a = 13.156(3) angstrom, b = 7.5436(15) angstrom, c = 9.6982(19) angstrom, beta = 130.96(3)degrees, Z = 4. Crystal data for 2: C16H14N2O6Ni, orthorhombic Pna2(1), a = 9.6113(19) angstrom, b = 19.691(4) angstrom, c = 8.0944(16) angstrom, Z = 4. Compound I is constructed from [Ni(H2O)(C4H4O5)] sheets pillared through beta-carboxylate groups into a 3D framework, which exhibits a diamond-like network. Compound 2 exhibits a 3D supramolecular network. To our knowledge, compound 1 represents the first diamond-like topology in the system of metal malate. Other characterizations by elemental analysis, IR and TG are also described. The magnetic behavior of compound 1 has been studied. (c) 2005 Elsevier Inc. All rights reserved.

引用

页码：776 / 781

页数：6

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