Spin Structure Change in Co-Substituted BiFeO3

被引:28
|
作者
Yamamoto, Hajime [1 ]
Kihara, Takumi [2 ,5 ]
Oka, Kengo [3 ]
Tokunaga, Masashi [2 ]
Mibu, Ko [4 ]
Azuma, Masaki [1 ]
机构
[1] Tokyo Inst Technol, Lab Mat & Struct, Yokohama, Kanagawa 2268503, Japan
[2] Univ Tokyo, Inst Solid State Phys, Kashiwa, Chiba 2778581, Japan
[3] Chuo Univ, Depertment Appl Chem, Fac Sci & Engn, Bunkyo Ku, Tokyo 1128551, Japan
[4] Nagoya Inst Technol, Grad Sch Engn, Nagoya, Aichi 4668555, Japan
[5] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan
基金
日本学术振兴会;
关键词
MAGNETIC CONTROL; TEMPERATURE; MOSSBAUER;
D O I
10.7566/JPSJ.85.064704
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The spin structure in BiFe1-xCoxO3 (x = 0.05, 0.10, 0.15, 0.20) was investigated as a function of Co substitution, temperature, and magnetic field. It was found that the cycloidal spin structure of BiFeO3 changed to a collinear one with spin canting and composition-independent spontaneous magnetization of similar to 0.25 mu B/f.u. for the Co substituted samples on heating. The collinear phase was stabilized under magnetic fields. The spin structure change was clarified also by the temperature dependence of Fe-57 Mossbauer spectra, and the results indicated the first order nature of this transition.
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页数:4
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