Crystal structure of hexacyanoferrato(III)bis(μ-cyano){1,3-bis-[(4-methyl-5-imidazol-1-yl)ethylideneamino]propan-2-ol}copper(II) hexacyanoferrato(III)-μ-cyano-{1,3-bis[(4-methyl-5-imidazol-1-yl)-ethylideneamino]propan-2-ol}cuprate(II) tetradecahydrate

被引:0
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作者
Long, LS
Ren, YP
Huang, RB
Zheng, LS
Chen, XM
Ng, SW [1 ]
机构
[1] Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China
[2] Zhongshan Univ, Dept Chem, Guangzhou 510275, Peoples R China
[3] Univ Malaya, Inst Postgrad Studies, Kuala Lumpur 50603, Malaysia
关键词
crystal structure; copper hexacyanatoferrate(III) complex;
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structure of hexacyanoferrato(III)bis(mu-cyano){1,3-bis[(4-methyl-5-imidazol-1-yl)ethylideneamino]propan-2-ol}copper(II) hexacyanoferrato(III)-mu-cyano-{1,3-bis[(4-methyl-5-imidazol-1-yl)ethylideneamino]propan-2-ol}cuprate(II) tetradecahydrate consists of trinuclear cations and dinuclear anions whose copper atoms show square pyramidal and iron atoms octahedral coordination. The cations and anions are linked by hydrogen bonds involving 14 lattice water molecules in a network architecture. Crystals of the C51H82Cu3Fe2N30O17 belong to the triclinic P (1) over bar space group [a = 13.700(2), b = 13.881(2), c = 21.431(3) Angstrom; alpha = 76.96(1), beta = 83.07(1), gamma = 74.70(1)degrees].
引用
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页码:19 / 22
页数:4
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